This would be the wiring for that section of your RV but be aware that there may have been after market items to connect the two battery groups together, so watch for anything like that iof you are not first owner.
https://www.winnebago.com/Files/File.../000027700.pdf
Page one gives the layout and where to find the mode solenoid, while page 3 gets down to the detailed wiring. Looks like you have the three wire solenoid and that means wire LR is the control wiring from the dash switch or ignition hot. Your system feeds power in on LR and through coil and uses an internal connection to get to the ground via the metal case. Removing LR from the small center post will disable this connection, both for the "boost" use and also foring charging the coach battery as we drive.
The item sometimes added is like a Trik-L-Start, etc and putting it on the solenoid or at the batteries are the two common places to add this mod. Small black box with three single wires to connect to each battery.
Unless there is some reason, I would not disconnect the disconnect relay as it is not involved in anything other than disconnecting the battery when stored.